Controlled electrodeposition of CoMoSx on carbon cloth: A 3D cathode for highly-efficient electrocatalytic hydrogen evolution. (19th February 2016)

• Record Type: Journal Article
• Authors: Zhang, Nan; Ma, Weiguang; Jia, Fei; Wu, Tongshun; Han, Dongxue; Niu, Li
• Is Part Of: International journal of hydrogen energy. Volume 41:Number 6(2016)
• Page Start: 3811
• Page End: 3819
• Publication Date: 2016-02-19
• Subjects: Binary metal sulfide -- Electrodeposition -- CoMoSx -- Electrocatalyst -- Hydrogen evolution reaction; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2015.12.173
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: Three-dimensional (3D) hydrogen evolution reaction (HER) catalysts are admirable for their advantages of enhanced electrolyte diffusion, more efficient utilization of active sites and easy release of hydrogen bubbles. In this work, the binder-free 3D cathode CoMoSx /CC has been successfully fabricated with the employment of 3D electrode, carbon cloth (CC). CoMoSx film was successfully deposited on CC with controllable morphology and thickness by the convenient co-electrodeposition process. Moreover, the deposition conditions have been optimized systematically. CoMoSx /CC fabricated under optimum conditions has achieved excellent HER performance with a small onset overpotential of 100 mV. It needed only 100, 125 and 180 mV overpotential (vs. RHE) to reach the current density of 10, 20 and 100 mA/cm 2 respectively, which performed the highest electrocatalytic activity among binary metal sulfide HER catalysts ever reported. Graphical abstract: The 3D HER cathode, CoMoSx /CC, has been successfully fabricated by the co-electrodeposition process. By regulating the thickness and morphology of CoMoSx film, superior HER performance has been achieved. Highlights: By electrodeposition method, CoMoSx /CC has been fabricated for HER. The thickness and morphology of CoMoSx on CC are controllable. Excellent HER performance has been achieved by CoMoSx /CC.