1, 2, 4-Diazaphospholide complexes of yttrium(iii), dysprosium(iii), erbium(iii), and europium(ii, iii): synthesis, X-ray structural characterization, and EPR analysis. Issue 3 (15th December 2015)

• Record Type: Journal Article
• Authors: Wang, Yongli; Guo, Wenzhen; Liu, Dongling; Yang, Ying; Zheng, Wenjun
• Is Part Of: Dalton transactions. Volume 45:Issue 3(2016)
• Page Start: 899
• Page End: 903
• Publication Date: 2015-12-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt04285b
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Heteroleptic, charge-separated heterobimetallic, and polymeric alkali metal ate complexes of 1, 2, 4-diazaphospholide yttrium(iii ), dysprosium(iii ), erbium(iii ), europium(iii ) and europium(ii ) were prepared. Abstract : Several structurally characterized heteroleptic, charge-separated heterobimetallic, and polymeric alkali metal ate complexes of 1, 2, 4-diazaphospholide Y(iii ), Dy(iii ), Er(iii ), Eu(iii ), and Eu(ii ) were prepared via the reaction of MCl3 and K[3, 5-R2 dp] in varied ratios at 200–220 °C (M = Y, Dy, Er, Eu; R = t Bu, Ph).