Delivering carbide ligands to sulfide-rich clusters. Issue 10 (23rd November 2015)
- Record Type:
- Journal Article
- Title:
- Delivering carbide ligands to sulfide-rich clusters. Issue 10 (23rd November 2015)
- Main Title:
- Delivering carbide ligands to sulfide-rich clusters
- Authors:
- Reinholdt, Anders
Herbst, Konrad
Bendix, Jesper - Abstract:
- Abstract : The propensity of the terminal ruthenium carbide Ru(C)Cl2 (PCy3 )2 (RuC ) to form carbide bridges to electron-rich transition metals enables synthetic routes to metal clusters with coexisting carbide and sulfide ligands. Abstract : The propensity of the terminal ruthenium carbide Ru(C)Cl2 (PCy3 )2 (RuC ) to form carbide bridges to electron-rich transition metals enables synthetic routes to metal clusters with coexisting carbide and sulfide ligands. Electrochemical experiments show the RuC ligand to exert a relatively large electron-withdrawing effect compared with PPh3, effectively shifting redox potentials.
- Is Part Of:
- Chemical communications. Volume 52:Issue 10(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 10(2016)
- Issue Display:
- Volume 52, Issue 10 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 10
- Issue Sort Value:
- 2016-0052-0010-0000
- Page Start:
- 2015
- Page End:
- 2018
- Publication Date:
- 2015-11-23
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc08918b ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 757.xml