Selective reduction of carbon dioxide to bis(silyl)acetal catalyzed by a PBP-supported nickel complex12. Issue 10 (22nd December 2015)

• Record Type: Journal Article
• Authors: Ríos, Pablo; Curado, Natalia; López-Serrano, Joaquín; Rodríguez, Amor
• Is Part Of: Chemical communications. Volume 52:Issue 10(2016)
• Page Start: 2114
• Page End: 2117
• Publication Date: 2015-12-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc09650b
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have been developed for this reaction. Abstract : The selective reduction of CO2 to the formaldehyde level remains an important challenge and to date only a few catalysts have been developed for this reaction. Herein, we report an efficient catalyst that consists of a bis(phosphino)boryl nickel hydride complex in combination with B(C6 F5 )3, for the highly selective hydrosilation of CO2 to bis(silyl)acetal derivatives.