A water-soluble metal–organic complex array as a multinuclear heterometallic peptide amphiphile that shows unconventional anion dependency in its self-assembly. Issue 8 (12th November 2015)

• Record Type: Journal Article
• Authors: Sukul, Pradip K.; Bose, Purnandhu; Takei, Toshiaki; Yaghi, Omar M.; He, Ying; Lee, Myongsoo; Tashiro, Kentaro
• Is Part Of: Chemical communications. Volume 52:Issue 8(2016)
• Page Start: 1579
• Page End: 1581
• Publication Date: 2015-11-12
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc08973e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Water-soluble metal–organic complex array1, bearing Ru(ii ), Pt(ii ) and Rh(iii ) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembling behaviours in aqueous media. Abstract : Water-soluble metal–organic complex array1, bearing Ru(ii ), Pt(ii ) and Rh(iii ) complexes at the side residues of the short peptide, exhibits anion and pH-responsive self-assembly behaviours in aqueous media. NaCl-induced aggregation of1 at neutral pH was suppressed in phosphate buffered saline containing a mixture of Cl −, HPO4 2− and H2 PO4 −, which is unconventional for a peptide amphiphile.