Topology-guided design of an anionic bor-network for photocatalytic [Ru(bpy)3]2+ encapsulation. Issue 9 (18th December 2015)

• Record Type: Journal Article
• Authors: Wang, Xuan; Lu, Weigang; Gu, Zhi-Yuan; Wei, Zhangwen; Zhou, Hong-Cai
• Is Part Of: Chemical communications. Volume 52:Issue 9(2016)
• Page Start: 1926
• Page End: 1929
• Publication Date: 2015-12-18
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc08614k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : An anionic metal–organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlyingbor -net is realized by the use of a tetrahedral [In(COO)4 ] − node and a judiciously designed trigonal planar linker. Abstract : An anionic metal–organic framework, PCN-99, has been synthesized through a topology-guided strategy; its underlyingbor -net is realized by the use of a tetrahedral [In(COO)4 ] − node and a judiciously designed trigonal planar linker. In light of its anionic nature, the inherent cuboctahedral cage and 1D channel make PCN-99 an excellent matrix to encapsulate the photocatalytic [Ru(bpy)3 ] 2+ .