Binding of calixarene-based Langmuir monolayers to mercury chloride is dependent on the amphiphile structure. Issue 11 (25th January 2016)

• Record Type: Journal Article
• Authors: Tulli, Ludovico G.; Wang, Wenjie; Rullaud, Vanessa; Lindemann, William R.; Kuzmenko, Ivan; Vaknin, David; Shahgaldian, Patrick
• Is Part Of: RSC advances. Volume 6:Issue 11(2016)
• Page Start: 9278
• Page End: 9285
• Publication Date: 2016-01-25
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra25470a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Langmuir monolayers of the tetra and two regioselective diamino-substituted amphiphilic calix[4]arenes show different recognition properties towards HgCl2 at the air–water interface, despite the macrocycles have highly similar structures. Abstract : Two amphiphilic calix[4]arenes bearing four dodecyl chains at the lower rim and two amino functions (vicinal and distal) at the para -phenolic positions have been synthesized. Surface-pressure versus molecular-area isotherms reveal that Langmuir monolayers of the two regioisomers show considerably distinct self-assembly behaviors at the air–water interface. Compression isotherms, Brewster angle microscopy and synchrotron-based X-ray near-total-reflection fluorescence, X-ray reflectivity and grazing incidence X-ray diffraction reveal that the monolayers of the two diamino calix[4]arene derivatives and those of their structural analogues bearing four amino moieties in para positions exhibit significant differences in their binding properties towards HgCl2 despite the structural and functional similarity among the macrocycles.