Access to side-chain carbon information in deuterated solids under fast MAS through non-rotor-synchronized mixing. Issue 2 (6th November 2015)

• Record Type: Journal Article
• Authors: Kulminskaya, Natalia; Vasa, Suresh Kumar; Giller, Karin; Becker, Stefan; Kwan, Ann; Sunde, Margaret; Linser, Rasmus
• Is Part Of: Chemical communications. Volume 52:Issue 2(2016)
• Page Start: 268
• Page End: 271
• Publication Date: 2015-11-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc07345f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : MOCCA provides comprehensive solid-state NMR side chain carbon correlations despite perdeuteration and fast sample rotation, thereby inducing minimal power dissipation. Abstract : We demonstrate the accessibility of aliphatic 13 C side chain chemical shift sets for solid-state NMR despite perdeuteration and fast MAS using isotropic, non-rotor-synchronized 13 C– 13 C mixing. Combined with amide proton detection, we unambiguously and sensitively detect whole side chain to backbone correlations for two proteins using around 1 mg of sample.