KI-catalyzed ring expansion reaction of trans-NH-ketoaziridines to new trans-oxazolidines. Issue 2 (13th January 2016)

• Record Type: Journal Article
• Authors: Samimi, Heshmat A.; Yamin, Bohari M.
• Is Part Of: Tetrahedron letters. Volume 57:Issue 2(2016)
• Page Start: 223
• Page End: 225
• Publication Date: 2016-01-13
• Subjects: Aziridines -- Regio-controlled -- Oxazolidine -- Ring expansion; Chemistry, Organic -- Periodicals; 547.005
• DOI: 10.1016/j.tetlet.2015.12.025
• Languages: English
• ISSNs: 0040-4039

Abstract

Graphical abstract: Abstract: In this work, the synthesis of a new class of trans -oxazolidines by the regio- and stereocontrolled reaction of NH-ketoaziridines with phenylisocyanate is reported. A plausible mechanism has been proposed.