Cleavage of carbon suboxide to give ketenylidene and carbyne ligands at a reactive tungsten site: a theoretical mechanistic study. Issue 5 (6th January 2016)

• Record Type: Journal Article
• Authors: Pu, Liang; Zhang, Zhong; Li, Qian-shu; King, R. Bruce
• Is Part Of: RSC advances. Volume 6:Issue 5(2016)
• Page Start: 4014
• Page End: 4021
• Publication Date: 2016-01-06
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra19003g
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : The reaction of (MePPh2 )4 WCl2 with C3 O2 results in stepwise cleavage of the two CC double bonds in C3 O2 to give tungsten complexes containing phosphinoketenylidene and phosphinocarbyne ligands. The mechanism of this has been elucidated using density functional theory. Abstract : Reaction of (MePPh2 )4 WCl2 with C3 O2 has been shown experimentally to result in stepwise cleavage of the two CC double bonds in C3 O2 to give successively tungsten complexes containing phosphinoketenylidene and phosphinocarbyne ligands. The mechanism of such processes has been elucidated by density functional theory methods for the L4 WCl2 (L = PMe3, PMePh2 ) systems. The triplet L4 WCl2 reagents are found to proceed to singlet intermediates and products in a reaction sequence involving dissociation of a phosphine ligand, a triplet → singlet intersystem crossing, an initial CC bond cleavage and a free phosphine attachment transition state. The first step is the rate-determining step with a Gibbs free energy barrier of 19.8 kcal mol −1, and the formation of the stable phosphinoketenylidene intermediate is thermodynamically favorable. Further reaction of the phosphinoketenylidene intermediate to give the final phosphinocarbyne product is unusual because it is thermodynamically disfavored but kinetically feasible. The key steps involve loss of another phosphine ligand to give the transition state involving the cleavage of the second CC bond of C3 O2 .