Molecular view modeling of atmospheric organic particulate matter: Incorporating molecular structure and co-condensation of water. (December 2015)

• Record Type: Journal Article
• Authors: Pankow, James F.; Marks, Marguerite C.; Barsanti, Kelley C.; Mahmud, Abdullah; Asher, William E.; Li, Jingyi; Ying, Qi; Jathar, Shantanu H.; Kleeman, Michael J.
• Is Part Of: Atmospheric environment. Volume 122(2015)
• Page Start: 400
• Page End: 408
• Publication Date: 2015-12
• Subjects: Organic particulate matter -- OPM -- Organic aerosol -- OA -- Secondary organic aerosol -- SOA -- Absorption model -- RH effects -- Water -- Co-condensation of water; Air -- Pollution -- Periodicals; Air -- Pollution -- Meteorological aspects -- Periodicals; 551.51
• DOI: 10.1016/j.atmosenv.2015.10.001
• Languages: English
• ISSNs: 1352-2310

Abstract

Abstract: Most urban and regional models used to predict levels of organic particulate matter (OPM) are based on fundamental equations for gas/particle partitioning, but make the highly simplifying, anonymized-view (AV) assumptions that OPM levels are not affected by either: a) the molecular characteristics of the condensing organic compounds (other than simple volatility); or b) co-condensation of water as driven by non-zero relative humidity (RH) values. The simplifying assumptions have allowed parameterized chamber results for formation of secondary organic aerosol (SOA) (e.g., "two-product" (2p) coefficients) to be incorporated in chemical transport models. However, a return towards a less simplistic (and more computationally demanding) molecular view (MV) is needed that acknowledges that atmospheric OPM is a mixture of organic compounds with differing polarities, water, and in some cases dissolved salts. The higher computational cost of MV modeling results from a need for iterative calculations of the composition-dependent gas/particle partition coefficient values. MV modeling of OPM that considered water uptake (but not dissolved salts) was carried out for the southeast United States for the period August 29 through September 7, 2006. Three model variants were used at three universities: CMAQ-RH-2p (at PSU), UCD/CIT-RH-2p (at UCD), and CMAQ-RH-MCM (at TAMU). With the first two, MV structural characteristics (carbon number and numbers of functional groups) were assigned to each of the 2p products used in CMAQv.4.7.1 such that resulting predicted K p, i values matched those in CMAQv.4.7.1. When water uptake was allowed, most runs assumed that uptake occurred only into the SOA portion, and imposed immiscibility of SOA with primary organic aerosol (POA). (POA is often viewed as rather non-polar, while SOA is commonly viewed as moderately-to-rather polar. Some runs with UCD/CIT-RH-2p were used to investigate the effects of POA/SOA miscibility.) CMAQ-RH-MCM used MCM to generate oxidation products, and assumed miscibility of SOA and POA. In a ∼500 km wide band from Louisiana through to at least North Carolina, CMAQ-RH-2p and UCD/CIT-RH-2p predicted that water uptake can increase SOA levels by as much as 50–100% (from a range of ∼1–2 μg m −3 to a range of ∼1–4 μg m −3 ). CMAQ-RH-MCM predicted much lower effects of water uptake on SOA levels (<10% increase). The results from CMAQ-RH-2p and UCD/CIT-RH-2p are considered more reflective of reality. In the Alabama/Georgia hotspot, both CMAQ-RH-2p and UCD/CIT-RH-2p predicted aerosol water levels that are up to nearly half the predicted SOA levels, namely ∼0.5–2 μg m −3 . Such water levels in SOA will affect particle optical properties, viscosity, gas/particle partitioning times, and rates of hydrolysis and water elimination reactions. Highlights: Current 3-D transport models use anonymized view modeling of organic particulate matter (OPM). Anonymized view modeling assigns only a volatility (vapor pressure) to each OPM constituent. Anonymized view modeling cannot consider effects of water uptake on OPM levels. Molecular view modeling assigns structural features to each OPM constituent. Molecular view modeling can consider effects of water uptake on OPM levels and OPM properties.