Fabrication of Nickel/nanodiamond/boron-doped diamond electrode for non-enzymatic glucose biosensor. (1st January 2016)

• Record Type: Journal Article
• Authors: Dai, Wei; Li, Mingji; Gao, Sumei; Li, Hongji; Li, Cuiping; Xu, Sheng; Wu, Xiaoguo; Yang, Baohe
• Is Part Of: Electrochimica acta. Volume 187(2016)
• Page Start: 413
• Page End: 421
• Publication Date: 2016-01-01
• Subjects: Nickel nanosheet -- Nanodiamond -- Boron-doped diamond -- Non-enzymatic biosensor -- Glucose; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.11.085
• Languages: English
• ISSNs: 0013-4686

Abstract

Highlights: Nanodiamonds (NDs) were electrophoretically deposited on the BDD film. The NDs significantly extended the potential window. Ni/NDs/BDD electrode was prepared by electrodeposition. The electrode shows good catalytic activity for glucose oxidation. Abstract: A stable and sensitive non-enzymatic glucose sensor was prepared by modifying a boron-doped diamond (BDD) electrode with nickel (Ni) nanosheets and nanodiamonds (NDs). The NDs were electrophoretically deposited on the BDD surface, and acted as nucleation sites for the subsequent electrodeposition of Ni. The morphology and composition of the modified BDD electrodes were characterized by field-emission scanning electron microscopy and energy-dispersive X-ray spectroscopy, respectively. The Ni nanosheet-ND modified BDD electrode exhibited good current response towards the non-enzymatic oxidation of glucose in alkaline media. The NDs significantly extended the potential window. The response to glucose was linear over the 0.2–1055.4-μM range. The limit of detection was 0.05 μM, at a signal-to-noise ratio of 3. The Ni nanosheet-ND/BDD electrode exhibited good selectivity, reproducibility and stability. Its electrochemical performance, low cost and simple preparation make it a promising non-enzymatic glucose sensor.