Electrodeposition behavior of aluminum from urea-acetamide-lithium halide low-temperature molten salts. (10th December 2015)

• Record Type: Journal Article
• Authors: Li, Min; Gao, Bingliang; Chen, Wenting; Liu, Chengyuan; Wang, Zhaowen; Shi, Zhongning; Hu, Xianwei
• Is Part Of: Electrochimica acta. Volume 185(2015)
• Page Start: 148
• Page End: 155
• Publication Date: 2015-12-10
• Subjects: Aluminum -- Electrodeposition -- Urea-acetamide-lithium halide -- Cyclic voltammetry -- Chronoamperometry; Electrochemistry -- Periodicals; Electrochemistry, Industrial -- Periodicals; 541.37
• DOI: 10.1016/j.electacta.2015.10.112
• Languages: English
• ISSNs: 0013-4686

Abstract

Abstract: Urea-acetamide-lithium halide (LiBr, LiCl, LiF) low-temperature molten salts were used as the electrolytes to study the electrodeposition of aluminum on a tungsten electrode. Al(III) was introduced into the salts by the addition of AlCl3 . The reduction potential of Al(III) is dependent on the molar ratio of AlCl3 /(urea + acetamide). The nucleation mechanism of aluminum on the tungsten electrode was determined to be three-dimensional instantaneous nucleation with diffusion-controlled growth at 333 K. Aluminum coatings were prepared at different cathodic potentials (from −0.10 V to −0.25 V) and different temperatures (from 313 K to 343 K) in urea-acetamide-LiBr molten salt. Scanning electron microscope (SEM) and X-ray diffraction (XRD) were used to characterize the surface of the deposits. The SEM images indicate that the morphologies of the aluminum deposits are dependent on the deposition potential and temperature. The XRD analysis confirms that the obtained deposits are pure aluminum.