A carbon–carbon hybrid – immobilizing carbon nanodots onto carbon nanotubes12. Issue 12 (3rd September 2015)

• Record Type: Journal Article
• Authors: Strauss, Volker; Margraf, Johannes T.; Clark, Timothy; Guldi, Dirk M.
• Is Part Of: Chemical science. Volume 6:Issue 12(2015:Dec.)
• Page Start: 6878
• Page End: 6885
• Publication Date: 2015-09-03
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5sc02728d
• Languages: English
• ISSNs: 2041-6520

Abstract

Abstract : The thrust of this work is to integrate small and uniformly sized carbon nanodots (CNDs) with single-walled carbon nanotubes of different diameters as electron acceptors and electron donors, respectively, and to test their synergetic interactions in terms of optoelectronic devices. Abstract : The thrust of this work is to integrate small and uniformly sized carbon nanodots (CNDs) with single-walled carbon nanotubes (SWCNT) of different diameters as electron donors and electron acceptors, respectively, and to test their synergetic interactions in terms of optoelectronic devices. CNDs (denoted p CNDs, where p indicates pressure) were prepared by pressure-controlled microwave decomposition of citric acid and urea. p CNDs were immobilized on single-walled carbon nanotubes by wrapping the latter with poly(4-vinylbenzyl trimethylamine) (PVBTA), which features positively charged ammonium groups in the backbone. Negatively charged surface groups on the CNDs lead to attractive electrostatic interactions. Ground state interactions between the CNDs and SWCNTs were confirmed by a full-fledged photophysical investigation based on steady-state and time-resolved techniques. As a complement, charge injection into the SWCNTs upon photoexcitation was investigated by ultra-short time-resolved spectroscopy.