Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid. Issue 12 (29th September 2015)
- Record Type:
- Journal Article
- Title:
- Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid. Issue 12 (29th September 2015)
- Main Title:
- Highly efficient, selective, and durable photocatalytic system for CO2 reduction to formic acid
- Authors:
- Tamaki, Yusuke
Koike, Kazuhide
Ishitani, Osamu - Abstract:
- Abstract : Photocatalytic reduction of CO2 to formic acid with high efficiency, durability, and rate. Abstract : We discovered an extremely suitable sacrificial electron donor, 1, 3-dimethyl-2-( o -hydroxyphenyl)-2, 3-dihydro-1 H -benzo[ d ]imidazole, for the selective photocatalytic reduction of CO2 to formic acid using a Ru(ii )–Ru(ii ) supramolecular photocatalyst. The efficiency, durability, and rate of photocatalysis are significantly increased ( Φ HCOOH = 0.46, TONHCOOH = 2766, TOFHCOOH = 44.9 min −1 ) in comparison with those using 1, 3-dimethyl-2-phenyl-2, 3-dihydro-1 H -benzo[ d ]imidazole or 1-benzyl-1, 4-dihydronicotinamide.
- Is Part Of:
- Chemical science. Volume 6:Issue 12(2015:Dec.)
- Journal:
- Chemical science
- Issue:
- Volume 6:Issue 12(2015:Dec.)
- Issue Display:
- Volume 6, Issue 12 (2015)
- Year:
- 2015
- Volume:
- 6
- Issue:
- 12
- Issue Sort Value:
- 2015-0006-0012-0000
- Page Start:
- 7213
- Page End:
- 7221
- Publication Date:
- 2015-09-29
- Subjects:
- Chemistry -- Periodicals
540.5 - Journal URLs:
- http://pubs.rsc.org/en/Journals/JournalIssues/SC ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5sc02018b ↗
- Languages:
- English
- ISSNs:
- 2041-6520
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3151.490000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 9.xml