Atomically precise growth of sodium titanates as anode materials for high-rate and ultralong cycle-life sodium-ion batteries. Issue 48 (23rd November 2015)

• Record Type: Journal Article
• Authors: Liu, Jian; Banis, Mohammad N.; Xiao, Biwei; Sun, Qian; Lushington, Andrew; Li, Ruying; Guo, Jinghua; Sham, Tsun-Kong; Sun, Xueliang
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 48(2015)
• Page Start: 24281
• Page End: 24288
• Publication Date: 2015-11-23
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5ta08435k
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : An atomic layer deposition technique was applied to fabricate sodium titanates as high performance anode materials for sodium-ion batteries. Abstract : Sodium-ion batteries (SIBs) have received increasing attention for applications in large-scale energy storage systems due to their low cost, high energy density, and high abundance of the sodium element. Nanosizing electrode materials becomes a key strategy to overcome the problems resulting from the sluggish kinetics of large sodium ions, thereby achieving good performance in SIBs. Herein, we developed an atomic layer deposition (ALD) approach for atomically precise fabrication of sodium titanate anode materials. This ALD process shows excellent controllability over the growth rate, film thickness, composition of sodium titanates, and high flexibility of coating uniform sodium titanate films onto various dimensions of substrates. Moreover, the amorphous sodium titanate deposited on carbon nanotubes exhibits high specific capacity, excellent rate capability, and ultra-long cycling life (∼100 mA h g −1 after 3500 cycles). It is expected that the ALD approach developed herein can be extended to well-defined fabrication of other sodium-containing electrode materials for SIBs.