Spectroscopic properties and energy transfer mechanism in Dy3+/Tm3+ codoped fluoroaluminate glasses modified by TeO2. Issue 1 (January 2016)

• Record Type: Journal Article
• Authors: Huang, Feifei; Tian, Ying; Chen, Danping; Xu, Shiqing; Zhang, Junjie
• Is Part Of: Ceramics international. Volume 42:Issue 1:Part A(2016)
• Page Start: 132
• Page End: 137
• Publication Date: 2016-01
• Subjects: Mid-infared -- Fluorotellurite glass -- Judd–Ofelt -- Energy transfer; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2015.08.031
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: This paper investigates 2.9 μm emission properties and energy transfer processes in the Dy 3+ /Tm 3+ codoped fluorotellurite glass. The measured absorption spectra demonstrate that the codoped sample can be efficiently pumped by an 800 nm excitation. Judd–Ofelt and radiative parameters are calculated and discussed. Higher spontaneous emission probability (39.6 S −1 ) provides a better probability to obtain laser action. Obvious 2.9 μm emission of Dy 3+ : 6 H13/2 → 6 H15/2 transition is observed after codoping with Tm 3+ and the optimum ratio in this system is 1:1. Energy transfer processes between the two ions are discussed and the related microscopic interaction parameters are calculated. Hence, these results indicate that the Dy 3+ /Tm 3+ codoped fluorotellurite glass is a suitable material for developing solid state laser at approximately 3.0 μm.