Gallium(iii)corrole–BODIPY hybrid: novel photophysical properties and first observation of B–F⋯F interactions. Issue 48 (18th November 2015)

• Record Type: Journal Article
• Authors: Basumatary, Biju; Ramana Reddy, R. V.; Bhandary, Subhrajyoti; Sankar, Jeyaraman
• Is Part Of: Dalton transactions. Volume 44:Issue 48(2015)
• Page Start: 20817
• Page End: 20821
• Publication Date: 2015-11-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt03104d
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Anchoring a BODIPY onto Ga(iii )corrole via a meso -β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. Abstract : Anchoring a BODIPY onto Ga(iii )corrole via a meso -β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for a corrole derivative, due to unique packing. Compound4 hosts the first example of a novel B–F⋯F interaction as well.