A self-assembled Pd2L4 cage that selectively encapsulates nitrate. Issue 94 (13th October 2015)
- Record Type:
- Journal Article
- Title:
- A self-assembled Pd2L4 cage that selectively encapsulates nitrate. Issue 94 (13th October 2015)
- Main Title:
- A self-assembled Pd2L4 cage that selectively encapsulates nitrate
- Authors:
- Zhou, Li-Peng
Sun, Qing-Fu - Abstract:
- Abstract : A M2 L4 cage featuring a concise hydrophobic pocket wrapped up by anthracene panels provides a specific binding site for nitrate. Abstract : A M2 L4 cage with D 4 symmetry was self-assembled from four anthracene-bridged benzimidazole ligands and two Pd II ions. The cage features a concise hydrophobic pocket wrapped up by the anthracene walls with eight hydrogen-bond donors pointing inward, which provide a specific binding site for nitrate, with a binding affinity at least two orders of magnitude higher than all the other anions screened including halide anions, which have a very similar ionic radius and charge density.
- Is Part Of:
- Chemical communications. Volume 51:Issue 94(2015)
- Journal:
- Chemical communications
- Issue:
- Volume 51:Issue 94(2015)
- Issue Display:
- Volume 51, Issue 94 (2015)
- Year:
- 2015
- Volume:
- 51
- Issue:
- 94
- Issue Sort Value:
- 2015-0051-0094-0000
- Page Start:
- 16767
- Page End:
- 16770
- Publication Date:
- 2015-10-13
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c5cc07306e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 2773.xml