Molecular line lists: The ro-vibrational spectra of NaF and KF. (January 2016)

• Record Type: Journal Article
• Authors: Frohman, Daniel J.; Bernath, Peter F.; Brooke, James S.A.
• Is Part Of: Journal of quantitative spectroscopy & radiative transfer. Volume 169(2016:Jan.)
• Page Start: 104
• Page End: 110
• Publication Date: 2016-01
• Subjects: Molecular data -- Astronomical data bases -- Exoplanets -- High temperature systems; Spectrum analysis -- Periodicals; Radiation -- Periodicals; Analyse spectrale -- Périodiques; Rayonnement -- Périodiques; Radiation; Spectrum analysis; Periodicals; 543.0858
• DOI: 10.1016/j.jqsrt.2015.10.004
• Languages: English
• ISSNs: 0022-4073

Abstract

Abstract: Rotation–vibration line lists for 23 Na 19 F, 39 K 19 F, and 41 K 19 F in their ground electronic states are presented. Experimental data previously collected for infrared transitions up to v =8 and v =9 for KF[1] and NaF[2], respectively, and for pure rotational transitions have been used to construct potential energy curves to yield ro-vibrational energy levels. Dipole moment functions were generated from ab initio calculations using the SA-CASSCF and ACPF methods. Full line lists and partition functions are made available as supplementary data.