Β-Sialon:Eu phosphor-in-glass: a robust green color converter for high power blue laser lighting. Issue 41 (23rd September 2015)

• Record Type: Journal Article
• Authors: Zhu, Qiang-Qiang; Wang, Xiao-Jun; Wang, Le; Hirosaki, Naoto; Nishimura, Toshiyuki; Tian, Zi-Feng; Li, Qian; Xu, Yan-Zheng; Xu, Xin; Xie, Rong-Jun
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 41(2015)
• Page Start: 10761
• Page End: 10766
• Publication Date: 2015-09-23
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5tc02236c
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Green-emitting phosphor in glass (PiG) materials for high power blue laser lighting have been successfully synthesized by uniformly dispersing β-Sialon:Eu phosphor powders into the ZnO–B2 O3 –BaO–Al2 O3 glass matrix. Abstract : Solid state laser lighting is superior to white light-emitting diodes in brightness, efficiency and color gamut, which require thermally robust color converters that can be endured by high power blue laser irradiation. Due to this, the application of bulk phosphor-in-glass (PiG) luminescent materials could be of great interest. Here, we report a green-emitting PiG material by co-firing β-Sialon:Eu phosphor powders with the ZnO–B2 O3 –BaO–Al2 O3 glass frits at 630–660 °C for 20–80 min in air. The microstructure, photoluminescence spectra, quantum efficiency, transmittance and thermal quenching of the β-Sialon:Eu PiG materials were investigated. The microstructural analysis indicated that β-Sialon:Eu phosphor powders were uniformly dispersed in the glass matrix without any interfacial reactions. The luminescence efficiency and transparency of the PiG materials were largely dependent on the phosphor concentration, firing temperature and dwell time. Under the blue laser excitation, the optimized PiG sample consisting of 5 wt% β-Sialon:Eu showed a linear relationship between the luminous flux and the incident laser power when the blue laser flux density was below 0.7 W mm −2, indicating its potential applications in solid state laser lighting.