Taking steps forward in understanding the electrochemical behavior of Na2Ti3O7. Issue 44 (6th October 2015)

• Record Type: Journal Article
• Authors: Nava-Avendaño, J.; Morales-García, A.; Ponrouch, A.; Rousse, G.; Frontera, C.; Senguttuvan, P.; Tarascon, J.-M.; Dompablo, M. E. Arroyo-de; Palacín, M. R.
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 44(2015)
• Page Start: 22280
• Page End: 22286
• Publication Date: 2015-10-06
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5ta05174f
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : A combination of experiments and calculations allows grasping more information on the capacity fading upon cycling of the Na2 Ti3 O7 electrode material in Na batteries. Abstract : Na2 Ti3 O7 is an interesting negative electrode material for sodium ion batteries given its electrochemical capacity and low operation potential. Unfortunately its prospects of practical application are hindered by an unacceptable capacity fading upon cycling. In this work we combine experiments and DFT calculations to investigate the origin of such a phenomenon. Different electrode technologies and different electrolytes have been targeted for electrochemical testing while the stability of Na2 Ti3 O7 and the fully reduced Na4 Ti3 O7 has been studied. The calculated elastic constants and vibrational modes support the mechanical and dynamical stability of the Na4 Ti3 O7 structure. In situ XRD measurements corroborate the reversibility of the insertion reaction as no structural damage is detected after 50 cycles. An intriguing reactivity of Na2 Ti3 O7 with the electrolyte upon storage is observed, which coupled to electrochemical measurements points to this being the main factor behind capacity fading.