An efficient desulfitative C–C cross coupling of fused thiazolidine-2-thione with boronic acids and boronic acid pinacol esters: formation of fused thiazoles. Issue 105 (13th October 2015)

• Record Type: Journal Article
• Authors: Rajaguru, Kandasamy; Mariappan, Arumugam; Manjusri, Ramachandran; Muthusubramanian, Shanmugam; Bhuvanesh, Nattamai
• Is Part Of: RSC advances. Volume 5:Issue 105(2015)
• Page Start: 86832
• Page End: 86839
• Publication Date: 2015-10-13
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra17827d
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : An efficient Pd(0)-catalyzed Cu(i )-mediated desulfitative C–C cross-coupling of benzo-fused thiazolidine-2-thione with boronic acids under neutral conditions and boronic acid pinacol esters under basic conditions has been demonstrated. Abstract : An efficient Pd(0)-catalyzed Cu(i )-mediated desulfitative C–C cross-coupling of benzo-fused thiazolidine-2-thione with boronic acids under neutral Liebeskind–Srogl conditions is described. The desulfitative cross coupling of boronic acid pinacol esters has also been demonstrated with fused thiazolidine-2-thione under basic conditions to afford fused thiazoles with good to excellent yields.