Epoxy–silica nanocomposite interphase control using task-specific ionic liquids via hydrolytic and non-hydrolytic sol–gel processes. Issue 111 (26th October 2015)

• Record Type: Journal Article
• Authors: Donato, R. K.; Perchacz, M.; Ponyrko, S.; Donato, K. Z.; Schrekker, H. S.; Beneš, H.; Matějka, L.
• Is Part Of: RSC advances. Volume 5:Issue 111(2015)
• Page Start: 91330
• Page End: 91339
• Publication Date: 2015-10-26
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra18387a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Carboxylic-functionalized task-specific imidazolium ionic liquids (carboxylic-IL) presented selective high reactivities with epoxy-functionalized compounds, even in highly complex epoxy–silica nanocomposite systems. Abstract : Carboxylic-functionalized task-specific imidazolium ionic liquids (carboxylic-ILs) presented selective high reactivities with epoxy-functionalized compounds, even in highly complex epoxy–silica nanocomposite systems. The carboxylic-ILs induced the in situ covalent bonding with epoxy based materials and tuning of the nanocomposites' filler–matrix interphase when applied either via hydrolytic or non-hydrolytic sol–gel processes. Structural modifications in the carboxylic-ILs allowed fine morphology control and promoted the formation of well dispersed silica nanodomains. This approach resulted in nanocomposites with improved mechanical properties, without a negative effect on the glass transition temperature, for both rubbery and glassy epoxy–silica nanocomposite systems with a very small IL content (∼0.2 wt%). The best properties were achieved with the application of IL 1-carboxypropyl-3-methylimidazolium chloride, which produced a toughness increase of more than 7 times for the rubbery and almost twice for the glassy epoxy systems, when compared to their IL-free equivalents. These easy and quick procedures to produce imidazolium functionalized materials have the potential to open up a broad range of new conductive, responsive, smart and tunable reinforced materials.