Conversion of nitrous oxide to nitrogen by cobalt-substituted myoglobin. Issue 108 (20th October 2015)

• Record Type: Journal Article
• Authors: Rapson, Trevor D.; Warneke, Soeren; Musameh, Mustafa M.; Dacres, Helen; Macdonald, Ben C. T.; Trowell, Stephen C.
• Is Part Of: RSC advances. Volume 5:Issue 108(2015)
• Page Start: 89003
• Page End: 89008
• Publication Date: 2015-10-20
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra15036a
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : Turning myoglobin into a nitrous oxide reductase. Abstract : Developing technology to decrease greenhouse gas emissions is one of the greatest challenges we face in the 21 st century. Nitrous oxide (N2 O) is an important greenhouse gas, which is estimated to contribute 6% of the overall global warming effect. Herein we report the use of cobalt substituted heme proteins to reduce N2 O to nitrogen (N2 ). This catalysis was electrochemically driven using methyl viologen or benzyl viologen as electron transfer partners for cobalt myoglobin. Using bulk electrolysis we demonstrated the production of 15 N2 from 15 N2 . This catalysis, however, was noted to be poor, most likely due to oxidative damage to the protein scaffold.