Achieving plasmon reproducibility from surfactant free gold nanostar synthesis. (28th August 2015)
- Record Type:
- Journal Article
- Title:
- Achieving plasmon reproducibility from surfactant free gold nanostar synthesis. (28th August 2015)
- Main Title:
- Achieving plasmon reproducibility from surfactant free gold nanostar synthesis
- Authors:
- Ramsey, Jacob D.
Zhou, Lixia
Kyle Almlie, C.
Lange, Jordan D.
Burrows, Sean M. - Abstract:
- Abstract : The novelty and significance lies in the low temperature synthesis to improve reproducibility of the plasmonic response by a factor of at least two compared to current approaches. Abstract : Obtaining reproducible plasmon resonances from nanostars remains a challenge for both surfactant and surfactant-free syntheses. For any nanostar application, a plasmon band with a reproducible spectral profile and λ max is a fundamental criterion. In particular, synthesis of biocompatible gold nanostars will benefit from surfactant-free methods to alleviate concerns over the cytotoxicity of many surfactants used in current synthesis techniques and the relative ease of synthesis. In this paper, we analyze different surfactant-free nanostar synthesis conditions and their influence on achieving plasmon reproducibility. Plasmon reproducibility was judged via the standard deviation of the extinction spectra's λ max and the spectral bandwidth. The synthesis temperature was the most influential factor in producing gold nanostars with reproducible plasmons. Nanostars synthesized at 5 °C exhibited a statistically ( α = 0.05) smaller standard deviation in both their λ max and spectral bandwidth than nanostars synthesized at 25 °C. The reproducibility of the plasmon band was preserved even when the reaction conditions were adjusted to shift the position of the peak plasmon resonance. The high reproducibility of this approach, combined with the ease of synthesis, presents a significantAbstract : The novelty and significance lies in the low temperature synthesis to improve reproducibility of the plasmonic response by a factor of at least two compared to current approaches. Abstract : Obtaining reproducible plasmon resonances from nanostars remains a challenge for both surfactant and surfactant-free syntheses. For any nanostar application, a plasmon band with a reproducible spectral profile and λ max is a fundamental criterion. In particular, synthesis of biocompatible gold nanostars will benefit from surfactant-free methods to alleviate concerns over the cytotoxicity of many surfactants used in current synthesis techniques and the relative ease of synthesis. In this paper, we analyze different surfactant-free nanostar synthesis conditions and their influence on achieving plasmon reproducibility. Plasmon reproducibility was judged via the standard deviation of the extinction spectra's λ max and the spectral bandwidth. The synthesis temperature was the most influential factor in producing gold nanostars with reproducible plasmons. Nanostars synthesized at 5 °C exhibited a statistically ( α = 0.05) smaller standard deviation in both their λ max and spectral bandwidth than nanostars synthesized at 25 °C. The reproducibility of the plasmon band was preserved even when the reaction conditions were adjusted to shift the position of the peak plasmon resonance. The high reproducibility of this approach, combined with the ease of synthesis, presents a significant step towards achieving gold nanostars with reproducible plasmons for biological applications. For example, photodynamic therapy, biomedical imaging contrast agents, and biosensing will all benefit from the reproducibility of the nanostars plasmon bands. … (more)
- Is Part Of:
- New journal of chemistry. Volume 39:Number 12(2015:Dec.)
- Journal:
- New journal of chemistry
- Issue:
- Volume 39:Number 12(2015:Dec.)
- Issue Display:
- Volume 39, Issue 12 (2015)
- Year:
- 2015
- Volume:
- 39
- Issue:
- 12
- Issue Sort Value:
- 2015-0039-0012-0000
- Page Start:
- 9098
- Page End:
- 9108
- Publication Date:
- 2015-08-28
- Subjects:
- Chemistry -- Periodicals
Chimie -- Périodiques
540 - Journal URLs:
- http://www.rsc.org/ ↗
http://www.rsc.org/is/journals/current/newjchem/njc.htm ↗ - DOI:
- 10.1039/c5nj01590a ↗
- Languages:
- English
- ISSNs:
- 1144-0546
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 6084.319900
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 837.xml