Selective CO production by Au coupled ZnTe/ZnO in the photoelectrochemical CO2 reduction system. Issue 12 (28th September 2015)

• Record Type: Journal Article
• Authors: Jang, Youn Jeong; Jang, Ji-Wook; Lee, Jaehyuk; Kim, Ju Hun; Kumagai, Hiromu; Lee, Jinwoo; Minegishi, Tsutomu; Kubota, Jun; Domen, Kazunari; Lee, Jae Sung
• Is Part Of: Energy & environmental science. Volume 8:Issue 12(2015)
• Page Start: 3597
• Page End: 3604
• Publication Date: 2015-09-28
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c5ee01445j
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Au coupled ZnTe/ZnO-NW array is a new photocathode for selective CO production from CO2 . The remarkable effects of an Au are to form of a Schottky junction with ZnTe to improve band bending and provide the reaction center for CO2 reduction suppressing water reduction. Abstract : A gold-coupled ZnTe/ZnO-nanowire array is a new photocathode for selective CO2 reduction to CO. At −0.7 VRHE under simulated 1 sun illumination, its photocurrent (−16.0 mA cm −2 ) and incident photon-to-current conversion efficiency (97%) represent the highest among reported ZnTe photocathodes for CO2 reduction and dramatic enhancement from those of a bare electrode (−7.9 mA cm −2, 68%). In addition, the Au nanoparticles convert mainly-hydrogen-producing bare ZnTe/ZnO-nanowires into mainly-CO-producing photocathodes in photoelectrochemical CO2 reduction. The remarkable effects of the Au co-catalyst originate from the formation of a Schottky junction with ZnTe to improve charge separation and to provide reaction centers for CO2 reduction suppressing competing water reduction.