C–H activation in IrIII and N-demethylation in PtII complexes with mesoionic carbene ligands: examples of monometallic, homobimetallic and heterobimetallic complexes12. Issue 42 (7th October 2015)

• Record Type: Journal Article
• Authors: Maity, Ramananda; Tichter, Tim; van der Meer, Margarethe; Sarkar, Biprajit
• Is Part Of: Dalton transactions. Volume 44:Issue 42(2015)
• Page Start: 18311
• Page End: 18315
• Publication Date: 2015-10-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt03285g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Mononuclear Pt II and the first dinuclear Pt II complexes along with a cyclometalated heterobimetallic Ir III /Pd II complex bearing mesoionic carbene donor ligands are presented starting from the same bis-triazolium salt. Abstract : Mononuclear Pt II and the first dinuclear Pt II complexes along with a cyclometalated heterobimetallic Ir III /Pd II complex bearing mesoionic carbene donor ligands are presented starting from the same bis-triazolium salt. The mononuclear Pt II complex possesses a free triazole moiety which is generated from the corresponding triazolium salt through an N -demethylation reaction, whereas the mononuclear Ir III complex features an unreacted triazolium unit.