Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis. (19th January 2016)
- Record Type:
- Journal Article
- Title:
- Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis. (19th January 2016)
- Main Title:
- Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis
- Authors:
- Rong, Jian
Deng, Ling
Tan, Ping
Ni, Chuanfa
Gu, Yucheng
Hu, Jinbo - Abstract:
- Abstract: The radical fluoroalkylation of isocyanides with fluorinated sulfones is enabled by visible‐light photoredox catalysis. A wide range of readily available mono‐, di‐, and trifluoromethyl heteroaryl sulfones can thus be used as efficient radical fluoroalkylation reagents under mild conditions. This method not only describes a new synthetic application of fluorinated sulfones, but also provides a new route to fluoroalkyl radicals.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 8(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 8(2016)
- Issue Display:
- Volume 128, Issue 8 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 8
- Issue Sort Value:
- 2016-0128-0008-0000
- Page Start:
- 2793
- Page End:
- 2797
- Publication Date:
- 2016-01-19
- Subjects:
- Fluor -- Isocyanide -- Photoredoxkatalyse -- Radikalreaktionen -- Sulfone
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201510533 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1248.xml