Structural evolution of Ag–Cu nano-alloys confined between AlN nano-layers upon fast heating. Issue 42 (27th April 2015)

• Record Type: Journal Article
• Authors: Janczak-Rusch, J.; Chiodi, M.; Cancellieri, C.; Moszner, F.; Hauert, R.; Pigozzi, G.; Jeurgens, L. P. H.
• Is Part Of: Physical chemistry chemical physics. Volume 17:Issue 42(2015)
• Page Start: 28228
• Page End: 28238
• Publication Date: 2015-04-27
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c5cp00782h
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : The paper presents a first comprehensive experimental investigation of the structural evolution of eutectic Ag–Cu nano-alloys, as confined between inert AlN barriers in a nano-multilayered configuration, upon fast heating. Abstract : The structural evolution of a Ag–Cu/AlN nano-multilayer (NML), as prepared by magnetron-sputtering on a α-Al2 O3 substrate, was monitored during fast heating by real-time in situ XRD analysis (at the synchrotron), as well as by ex situ microstructural analysis using SEM, XPS and in-house XRD. The as-deposited NML is constituted of alternating nano-layers (thickness ≈ 10 nm) of a chemically inert AlN barrier and a eutectic Ag–Cu40at% nano-alloy. The nano-alloy in the as-deposited state is composed of a fcc matrix of Ag nano-grains (≈6 nm), which are supersaturated by Cu, and some smaller embedded Cu rich nano-grains (≈4 nm). Heating up to 265 °C activates segregation of Cu out of the supersaturated Ag nano-grains phase, thus initiating phase separation. At T > 265 °C, the phase-separated Cu metal partially migrates to the top NML surface, thereby relaxing thermally-accumulated compressive stresses in the confined alloy nano-layers and facilitating grain coarsening of (still confined) phase-separated nano-crystallites. Further heating and annealing up to 420 °C results in complete phase separation, forming extended Ag and Cu domains with well-defined coherent Ag/AlN interfaces. The observed outflow of Cu well below the eutectic melting point of the bulk Ag–Cu alloy might provide new pathways for designing low-temperature nano-structured brazing materials.