An open-framework beryllium phosphite with extra-large 18-ring channels. Issue 44 (15th October 2015)

• Record Type: Journal Article
• Authors: Wang, Guo-Ming; Li, Jin-Hua; Wei, Li; Han, Song-De; Zhao, Xiao-Meng; Bao, Zhen-Zhen
• Is Part Of: CrystEngComm. Volume 17:Issue 44(2015)
• Page Start: 8414
• Page End: 8417
• Publication Date: 2015-10-15
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c5ce01507c
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : We report herein a 3D interrupted beryllium phosphite open-framework with a low density (1.594 g cm −3 ), which is the first case of a beryllium phosphite framework containing extra-large 18-ring channels. Abstract : A novel open-framework beryllium phosphite, [H4 tren][Be6 (HPO3 )8 ]·(H2 O)3 (1, tren = tris(2-aminoethyl)amine), was synthesized under solvothermal conditions. Its structure features a 3D interrupted network with a low density (1.594 g cm −3 ), and1 represents the first example of a beryllium phosphite material with extra-large 18-ring channels.