Highly transparent poly(2-ethyl-2-oxazoline)-TiO2 nanocomposite coatings for the conservation of matte painted artworks. Issue 103 (7th October 2015)

• Record Type: Journal Article
• Authors: Colombo, A.; Gherardi, F.; Goidanich, S.; Delaney, J. K.; de la Rie, E. R.; Ubaldi, M. C.; Toniolo, L.; Simonutti, R.
• Is Part Of: RSC advances. Volume 5:Issue 103(2015)
• Page Start: 84879
• Page End: 84888
• Publication Date: 2015-10-07
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra10895k
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A nanocomposite coating based on TiO2 nanoparticles and poly(2-ethyl-2-oxazoline) is used as consolidant of matte paintings (such as temperas), by exploiting bulk scattering phenomenon to mimic the surface diffusive properties of the painted surface. Abstract : A nanocomposite coating based on TiO2 nanoparticles and poly(2-ethyl-2-oxazoline) is used as consolidant of matte painted surfaces (temperas, watercolors, modern paintings). The aim of this work is to provide advances in the conservation of these works of art, while preserving their optical appearance, in terms of colour and gloss. Fiber Optic Reflectance Spectroscopy (FORS) measurements of a painting-model (an acrylic black monochrome) treated with the nanocomposite coatings revealed that it is possible to match the optical appearance of the painted surface by tuning the amount of nanoparticles in the polymeric matrix. The requirement of retreatability of the material has been verified by removing the nanocomposite cast on the painted surface with aqueous solutions. FTIR and SEM/EDX measurements showed that almost no traces of the nanocomposite remained on the painted surface, allowing its use for the treatment of real paintings. Test were performed using a contemporary studio-model on canvas attributed to Agostino Bonalumi (1935–2013).