Addition of in situ reduced amidinato-methylaluminium chloride to acetylenes12. Issue 40 (23rd September 2015)

• Record Type: Journal Article
• Authors: Chlupatý, T.; Turek, J.; De Proft, F.; Růžičková, Z.; Růžička, A.
• Is Part Of: Dalton transactions. Volume 44:Issue 40(2015)
• Page Start: 17462
• Page End: 17466
• Publication Date: 2015-09-23
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt03128a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Addition of in situ reduced amidinato-methylaluminium chloride to acetylenes was observed. Whether the structure of the products contains an ethylene bridge or terminally bonded ethynyl groups, and the further reactivity of the products are closely related to the substituents on the CC group. Abstract : Two ethylene-bridged methylaluminium amidinates and one aluminium amidinate containing three terminal trimethylstannyl-ethynyl groups interconnected by π-coordinated potassium ions were prepared in situ . The re-oxidation of the ethylene-bridged compound by iodine followed by further reduction using the same activation procedure demonstrated the versatility of the approach. The reactivity of an ethylene-bridged methylaluminum amidinate towards HCl was examined to demonstrate the building block concept. DFT calculations were performed to gain insight into the mechanism of the in situ activation of diphenylacetylene.