Insight into the molecular dynamics of guest cations confined in deformable azido coordination frameworks. Issue 86 (14th September 2015)

• Record Type: Journal Article
• Authors: Du, Zi-Yi; Sun, Yu-Zhi; Chen, Shao-Li; Huang, Bo; Su, Yu-Jun; Xu, Ting-Ting; Zhang, Wei-Xiong; Chen, Xiao-Ming
• Is Part Of: Chemical communications. Volume 51:Issue 86(2015)
• Page Start: 15641
• Page End: 15644
• Publication Date: 2015-09-14
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc06863k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : The guest molecular dynamics confined in deformable azido coordination frameworks are revealed, one of which features unvaried/varied E a during its two structural phase transitions. Abstract : The molecular dynamics of encapsulated cations within perovskite-like coordination polymers [(CH3 )3 NH][M(N3 )3 ] (M = Mn, Cd) are investigated, which are well controlled by the confined space of a deformable azido framework. The Mn-based compound provides a rare example that features an unvaried/varied rotational energy barrier during its two different structural phase transitions.