5, 5′-Diamino-BIPHEP ligands bearing small selector units for non-covalent binding of chiral analytes in solution. Issue 86 (11th September 2015)

• Record Type: Journal Article
• Authors: Storch, G.; Siebert, M.; Rominger, F.; Trapp, O.
• Is Part Of: Chemical communications. Volume 51:Issue 86(2015)
• Page Start: 15665
• Page End: 15668
• Publication Date: 2015-09-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc06306j
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A dynamic axially chiral BIPHEP-ligand with 3, 5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Abstract : A dynamic axially chiral BIPHEP-ligand with 3, 5-dichlorobenzoyl amide selector units for non-covalent binding of phenylalanine derivatives has been developed. Interaction studies in solution were performed with rhodium(i ) complexes under exclusion of the metal being involved in binding. ( R ax, S Phe ) and ( S ax, S Phe ) adducts were observed as significantly separated species in NMR spectroscopy.