Non‐Classically Controlled Signs in a Circularly Polarised Luminescent Molecular Puppet: The Importance of the Wire Structure Connecting Binaphthyl and Two Pyrenes. Issue 1 (15th December 2015)

• Record Type: Journal Article
• Authors: Nakabayashi, Kazuki; Kitamura, Sayaka; Suzuki, Nozomu; Guo, Sibo; Fujiki, Michiya; Imai, Yoshitane
• Is Part Of: European journal of organic chemistry. Issue 1(2016)
• Page Start: 64
• Page End: 69
• Publication Date: 2015-12-15
• Subjects: Circular dichroism -- Luminescence -- Fluorescence -- Fused‐ring systems; Chemistry, Organic -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1002/ejoc.201501316
• Languages: English
• ISSNs: 1434-193X

Abstract

Abstract: The circularly polarised luminescence and circular dichroism signs of the blue circularly polarised luminescence generated by two photoexcited pyrenes as puppets are controlled by the wire structure of the C 2 ‐symmetric binaphthyl as puppeteer. The experimental results, though at variance with theoretical simulation, offer a rational design in the photoexcited and ground state chiralities of luminophores. Abstract : The circularly polarised luminescence and circular dichroism signs of the blue circularly polarised luminescence generated by two photoexcited pyrenes as puppets are controlled by the wire structure of the C 2 ‐symmetric binaphthyl as puppeteer.