Syntheses, Crystal Structure, and Photoluminescence Property of One Novel Compound Derived From Dicarboxylate and N-Donor Ligands. Issue 4 (2nd April 2016)

• Record Type: Journal Article
• Authors: Yan, Li; Sun, Mingzhe
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 4(2016)
• Page Start: 556
• Page End: 560
• Publication Date: 2016-04-02
• Subjects: crystal structure -- noncovalent interactions -- fluorescence -- infrared spectrum; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2015.1031012
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : One novel compound constructed from aromatic acid and N -heterocyclic ligands has been synthesized by hydrothermal reaction: [Mn(ipm)(1, 8-NDC)(H2 O)]2 (1 ) [ipm = 5-(1H-imidazo[4, 5-f][1, 10]phenanthrolin-2-yl)-2-methoxyphenol, 1, 8-NDC = naphthalene-1, 8-dicarboxylic acid]. The title compound was obtained by controlling the ratio of the starting materials and a reaction temperature at 170°C and was characterized by elemental analysis, IR, single-crystal X-ray diffraction, and thermogravimetric analysis (TGA). Single-crystal X-ray investigation reveals that compound1 is zero dimensional (0D) structure, and the existence of hydrogen bonds and π-π interactions lead the 0D to 1D chain framework. Hydrogen bonds interactions are powerful noncovalent intermolecular interactions for directing supramolecular architectures. TGA shows three clear courses of weight loss, which corresponds to the decomposition of different ligands. At room temperature, compound1 exhibits emission at 535 nm upon excitation at 325 nm. Fluorescent spectrum displays that compound1 is potential luminescent material.