Investigation of the spectral, optical and surface morphology properties of the N, N′‐Dipentyl‐3, 4, 9, 10‐perylenedicarboximide small molecule for optoelectronic applications†. (23rd July 2015)

• Record Type: Journal Article
• Authors: Gündüz, Bayram
• Is Part Of: Polymers for advanced technologies. Volume 27:Number 2(2016)
• Page Start: 144
• Page End: 155
• Publication Date: 2015-07-23
• Subjects: nanomaterials -- optical properties -- semiconductors -- solutions -- conductivity; Polymers -- Periodicals; 668.9
• DOI: 10.1002/pat.3607
• Languages: English
• ISSNs: 1042-7147

Abstract

Abstract : The spectral and optical properties of the solutions of the N, N ′‐Dipentyl‐3, 4, 9, 10‐perylenedicarboximide (PTCDI‐C5) small molecule for different molarities were investigated in detail. The significant spectral parameters such as molar/mass extinction coefficients, absorption coefficient, electric dipole line strength, and oscillator strength of the PTCDI‐C5 molecule were calculated. The absorption bands of PTCDI‐C5 show vibronic structures with seven peaks at 2.08, 2.35, 2.53, 2.70, 2.86, 3.32, and 3.86 eV, respectively. The electronic spectra of the PTCDI‐C5 can be characterized by two basic regions as visible and Soret band. Effects of the molarities on the significant many optical parameters were investigated in detail. The direct and indirect allowed optical band gaps of the PTCDI‐C5 decrease with increasing molarity. Then, surface morphology properties were investigated and calculated roughness parameters of the PTCDI‐C5 film. Finally, we discussed for optoelectronic applications of these parameters, and this study was compared with the similar and related studies in the literature. Copyright © 2015 John Wiley & Sons, Ltd.