A New Energetic Material and its Risk Research. (21st September 2015)

• Record Type: Journal Article
• Authors: Han, Zhiyue; Zhang, Yinghao; Yao, Qian; Du, Zhiming; He, Chunlin; Zhang, Jingchang
• Is Part Of: Journal of heterocyclic chemistry. Volume 53:Number 1(2016:Jan.)
• Page Start: 325
• Page End: 331
• Publication Date: 2015-09-21
• Subjects: Heterocyclic compounds -- Periodicals; 547.59
• DOI: 10.1002/jhet.2488
• Languages: English
• ISSNs: 0022-152X

Abstract

Abstract : Bis (1, 5‐diamino‐4‐methyl‐tetrazolium) azotetrazolate (BMDATZT ) was synthesized with high yield in this work. The yield is 97.46%. The structure was characterized by IR, 1 H NMR, and MS. The single crystal of BMDATZT2H2 O was first cultivated. The heat of formation, detonation pressure, and detonation velocity were first calculated. The crystalline density of BMDATZT2H2 O is 1.573 g/cm 3 .BMDATZT has high detonation pressure and detonation velocity ( P =25.06 GPa, D = 7.805 km s −1 ), which are higher than those of 2, 4, 6‐Trinitrotoluene (TNT). Its thermal and mechanical sensitivities are moderate. Therefore, it is a kind of insensitive nitrogen‐rich energetic ionic salt with good performance, and it has potential application prospect in gas generating agent, explosive and solid propellant. Abstract :