Palladium‐Catalyzed Olefination and Arylation of Polyfluoroarenes Using Molecular Oxygen as the Sole Oxidant. Issue 16 (29th October 2015)

• Record Type: Journal Article
• Authors: Huang, Qiufeng; Zhang, Xinyu; Qiu, Lin; Wu, Jiajun; Xiao, Hanbing; Zhang, Xiaofeng; Lin, Shen
• Is Part Of: Advanced synthesis & catalysis. Volume 357:Issue 16/17(2015)
• Page Start: 3753
• Page End: 3757
• Publication Date: 2015-10-29
• Subjects: arylation -- CH activation -- molecular oxygen -- olefination -- palladium; Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201500632
• Languages: English
• ISSNs: 1615-4150

Abstract

Abstract: The palladium‐catalyzed cross‐dehydrogenative‐coupling of polyfluoroarenes with alkenes or simple arenes has been developed. The approach is characterized by using atmospheric pressure of molecular oxygen as the sole oxidant, and provides a straightforward and environmentally benign route to functionalized polyfluoroarenes. Abstract :