A New Mo(VI) Complex of (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol: Synthesis, Characterization, and X-Ray Crystal Structure. Issue 6 (2nd June 2016)

• Record Type: Journal Article
• Authors: Sheikhshoaie, Iran; Ebrahimipour, S. Yousef; Shamsi, Somayeh
• Is Part Of: Synthesis and reactivity in inorganic, metal-organic, and nano-metal chemistry. Volume 46:Issue 6(2016)
• Page Start: 917
• Page End: 921
• Publication Date: 2016-06-02
• Subjects: Schiff base ligand -- Mo(VI) complex -- ONO donor -- crystal structure -- spectroscopic characterization; Inorganic compounds -- Synthesis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Organometallic compounds -- Synthesis -- Periodicals; Reactivity (Chemistry) -- Periodicals; Nanostructured materials -- Periodicals; 541.39
• DOI: 10.1080/15533174.2014.989612
• Languages: English
• ISSNs: 1553-3174

Abstract

Abstract : A tridentate ONO Schiff base ligand, (E)-2-(((5-hydroxypentyl)imino)methyl)-6-methoxyphenol [H2 L], and its Mo(VI) complex [MoL], have been synthesized and structurally characterized by elemental analysis, FT-IR, NMR, and UV–Vis spectroscopy. The structure of the Mo(VI) complex has been determined by single-crystal X-ray diffraction. This complex has octahedral geometry around central atom. Yellow crystals crystallize in orthorhombic, space group Pbca with a = 17.8718(10) Å, b = 17.4516(10) Å, c, 18.1872(10) Å and α = β = γ = 90°.