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ChemInform Abstract: Diastereoselective Construction of anti‐4, 5‐Disubstituted‐1, 3‐dioxolanes via a Bismuth‐Mediated Two‐Component Hemiacetal Oxa‐Conjugate Addition of γ‐Hydroxy‐α, β‐unsaturated Ketones with Paraformaldehyde. Issue 8 (February 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Diastereoselective Construction of anti‐4, 5‐Disubstituted‐1, 3‐dioxolanes via a Bismuth‐Mediated Two‐Component Hemiacetal Oxa‐Conjugate Addition of γ‐Hydroxy‐α, β‐unsaturated Ketones with Paraformaldehyde. Issue 8 (February 2016)
Main Title:
ChemInform Abstract: Diastereoselective Construction of anti‐4, 5‐Disubstituted‐1, 3‐dioxolanes via a Bismuth‐Mediated Two‐Component Hemiacetal Oxa‐Conjugate Addition of γ‐Hydroxy‐α, β‐unsaturated Ketones with Paraformaldehyde
Abstract: The obtained dioxolanes (III) can be subjected to stereodivergent reductions to afford syn, syn and syn, anti‐1, 2, 4‐triols (IV) and (V), respectively.