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ChemInform Abstract: Catalytic Asymmetric Formal Insertion of Aryldiazoalkanes into the C—H Bond of Aldehydes: Synthesis of Enantioenriched Acyclic α‐Tertiary Aryl Ketones. Issue 8 (February 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Catalytic Asymmetric Formal Insertion of Aryldiazoalkanes into the C—H Bond of Aldehydes: Synthesis of Enantioenriched Acyclic α‐Tertiary Aryl Ketones. Issue 8 (February 2016)
Main Title:
ChemInform Abstract: Catalytic Asymmetric Formal Insertion of Aryldiazoalkanes into the C—H Bond of Aldehydes: Synthesis of Enantioenriched Acyclic α‐Tertiary Aryl Ketones.
Abstract: A novel method is elaborated for the enantioselective synthesis of ketones (III), (V), and (VII) by reaction of aldehydes with aryldiazoalkanes in the presence of chiral (S)‐oxazaborolidinium triflate catalyst.