ChemInform Abstract: High‐Temperature Salt Flux Crystal Growth of new Lanthanide Molybdenum Oxides, Ln5Mo2O12 Ln: Eu, Tb, Dy, Ho, and Er: Magnetic Coupling within Mixed Valent Mo(IV/V) Rutile‐Like Chains. Issue 8 (February 2016)

• Record Type: Journal Article
• Authors: Cortese, Anthony J.; Abeysinghe, Dileka; Wilkins, Branford; Smith, Mark D.; Morrison, Gregory; zur Loye, Hans‐Conrad
• Is Part Of: ChemInform. Volume 47:Issue 8(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-02
• Subjects: molybdenum, Mo -- lanthanoids -- structure (solids and liquids) -- dielectric properties, magnetic properties; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201608017
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The title compounds are prepared in a molten salt flux (eutectic CsCl/NaCl) using 1:2:0.5 molar mixtures of Ln2 O3, MoO3, and Mo (evacuated silica tubes, 800 °C, 24 h; cooling to 400 °C at a rate of 0.1 °C/min).