Back Cover: Insights into the Major Reaction Pathways of Vapor‐Phase Hydrodeoxygenation of m‐Cresol on a Pt/HBeta Catalyst (ChemCatChem 3/2016). Issue 3 (February 2016)

• Record Type: Journal Article
• Authors: Sun, Qianqian; Chen, Guanyi; Wang, Hua; Liu, Xiao; Han, Jinyu; Ge, Qingfeng; Zhu, Xinli
• Is Part Of: ChemCatChem. Volume 8:Issue 3(2016)
• Page Start: 656
• Page End: 656
• Publication Date: 2016-02
• Subjects: hydrodeoxygenation -- hydrogenation -- m-cresol -- Pt/HBeta -- ring contraction; Catalysis -- Periodicals; 541.39505
• DOI: 10.1002/cctc.201600078
• Languages: English
• ISSNs: 1867-3880

Abstract

Abstract : The Cover shows the major reaction pathways of hydrodeoxygenation of m‐cresol to hydrocarbons on a bifunctional Pt/HBeta catalyst, consisting of both metal site (Pt) and Brønsted acid site (BAS). In their Full Paper, Sun et al. demonstrate that the reaction proceeds through both a direct deoxygenation path (DDO) to toluene and a hydrogenation‐deoxygenation path (HYD) to methylcyclohexane and ring contraction products. The selectivity between the two paths depends on competition between the initial rates of deoxygenation and hydrogenation of cresol. The apparent activation energy is positive for the DDO path, whereas it becomes negative for the HYD path. More information can be found in the Full Paper by Sun et al. onpage 551 in Issue 3, 2016 (DOI:10.1002/cctc.201501232 ).