High‐Energy, High‐Rate, Lithium–Sulfur Batteries: Synergetic Effect of Hollow TiO2‐Webbed Carbon Nanotubes and a Dual Functional Carbon‐Paper Interlayer. Issue 1 (5th October 2015)

• Record Type: Journal Article
• Authors: Hwang, Jang‐Yeon; Kim, Hee Min; Lee, Sang‐Kyu; Lee, Joo‐Hyeong; Abouimrane, Ali; Khaleel, Mohammad Ahmed; Belharouak, Ilias; Manthiram, Arumugam; Sun, Yang‐Kook
• Is Part Of: Advanced energy materials. Volume 6:Issue 1(2016)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2015-10-05
• Subjects: high power -- interlayer -- lithium–sulfur batteries -- porous carbon -- titanium dioxide; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201501480
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : A novel nanocomposite cathode consisting of sulfur and hollow‐mesoporous titania (HMT) embedded within carbon nanotubes (CNT), which is designated as S‐HMT@CNT, has been obtained by encapsulating elemental sulfur into the pores of hollow‐mesoporous, spherical TiO2 particles that are connected via CNT. A carbon‐paper interlayer, referred to as dual functional porous carbon wall (DF‐PCW), has been obtained by filling the voids in TiO2 spheres with carbon and then etching the TiO2 template with a chemical process. The DF‐PCW interlayer provides a medium for scavenging the lithium polysulfides and suppressing them from diffusing to the anode side when it is inserted between the sulfur cathode and the separator. Lithium–sulfur cells fabricated with the thus prepared S‐HMT@CNT cathode and the DF‐PCW interlayer exhibit superior performance due to the containment of sulfur in TiO2 and improved lithium–ion and electron transports. The Li–S cells display high capacity with excellent capacity retention at rates as high as 1C, 2C, and 5C rates. Abstract : A high‐capacity, high‐rate sulfur cathode is developed by encapsulating elemental sulfur into the pores of hollow‐mesoporous TiO2 particles that are connected via carbon nanotubes. A lithium‐sulfur cell consisting of such a nanocomposite cathode along with a dual functional carbon‐paper interlayer between the sulfur cathode and the separator exhibits high‐capacities at rates as high as 5 C‐rate with a good cycle life.