ChemInform Abstract: RhI/RhIII Catalyst‐Controlled Divergent Aryl/Heteroaryl C—H Bond Functionalization of Picolinamides with Alkynes. Issue 6 (21st January 2016)

• Record Type: Journal Article
• Authors: Martinez, Angel Manu; Echavarren, Javier; Alonso, Ines; Rodriguez, Nuria; Gomez Arrayas, Ramon; Carretero, Juan C.
• Is Part Of: ChemInform. Volume 47:Issue 6(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-01-21
• Subjects: isoquinoline derivatives -- carboxylic amides (benzene compounds) -- polyphenylalkene derivatives (stilbene derivatives) -- catalysis, phase‐transfer catalysis -- multicomponent reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201606184
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: When Rh(I) catalyst is used, the C—H bonds of aryl groups of picolinamides [e.g. (I)] are functionalized to give ortho‐olefinated benzylamines [e.g. (II)] or phenethylamines [e.g. (XIII)].