ChemInform Abstract: A Convenient Synthesis of New Biological Active 5‐Imino‐4‐thioxo‐2‐imidazolidinones Involving Acetonitrile Electrogenerated Base. Issue 4 (January 2016)

• Record Type: Journal Article
• Authors: Sbei, Najwa; Batanero, Belen; Barba, Fructuoso; Haouas, Beya; Fuentes, Luis; Benkhoud, Mohamed Lamine
• Is Part Of: ChemInform. Volume 47:Issue 4(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-01
• Subjects: imidazole derivatives -- thio compounds (acyclic compounds) -- multicomponent reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201604121
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Acetonitrile is electrolyzed to form cyanomethyl anion, which not only deprotonizes benzyl amines [e.g. (I)] to give a nitride intermediate, but also forms an organomagnesium compound with the magnesium anode.