Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers. Issue 1 (23rd November 2015)

• Record Type: Journal Article
• Authors: Ciganda, Roberto; Gu, Haibin; Castel, Patricia; Zhao, Penxiang; Ruiz, Jaime; Hernández, Ricardo; Astruc, Didier
• Is Part Of: Macromolecular rapid communications. Volume 37:Issue 1(2016)
• Page Start: 105
• Page End: 111
• Publication Date: 2015-11-23
• Subjects: cobalticenium -- electrochemistry -- ferrocene -- metallopolymers -- ring‐opening metathesis polymerization, ROMP; Macromolecules -- Periodicals; Polymers -- Periodicals; Chemistry -- Periodicals; 547.705
• DOI: 10.1002/marc.201500566
• Languages: English
• ISSNs: 1022-1336

Abstract

Abstract : Using the third‐generation Grubbs catalyst, the living ring‐opening metathesis polymerization of ferrocene/cobalticenium copolymers is conducted with theoretical numbers of 25 monomer units for each block, and their redox and electrochemical properties allow using the Bard–Anson electrochemical method to determine the number of metallocenyl units in each block. Abstract : Using the third‐generation Grubbs catalyst, the living ring‐opening metathesis polymerization of ferrocenyl/cobalticenium copolymers is conducted with theoretical numbers of 25 monomer units for each block, and their redox and electrochemical properties allow using the Bard–Anson electrochemical method to determine the number of metallocenyl units in each block.