ChemInform Abstract: Ag(I)‐Catalyzed Three‐Component Reaction of 2‐Alkynylbenzaldehydes, Amines, and Diazo Compounds. Issue 4 (January 2016)

• Record Type: Journal Article
• Authors: Xiao, Tiebo; Peng, Pai; Xie, Yang; Wang, Zhao‐yang; Zhou, Lei
• Is Part Of: ChemInform. Volume 47:Issue 4(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-01
• Subjects: azepine derivatives -- catalysis, phase‐transfer catalysis -- ring closure reactions, annulation reactions -- multicomponent reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201604159
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: A one‐pot three‐component cyclization of diazo compounds as nucleophiles with primary aromatic amines and alkynylbenzaldehydes gives 3‐benzazepines via a cascade imine—yne cyclization/nucleophilic addition/1, 2‐aryl migrations.